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3-methylbutanoyl-CoA H2O 3-methylglutaconyl-CoA lipoamide-E 3-methylbut-2-enoyl-CoA (S)-3-hydroxy-3-methylglutaryl-CoA HCO3- L-leucine FADH2 H+ lipoamide-E NADH L-glutamate acetoacetate 2-oxoglutarate FAD dihydrolipoamide-E S-(3-methylbutanoyl)-
dihydrolipoamide-E orthophosphate thiamine diphosphate NAD+ ATP 4-methyl-2-oxopentanoate thiamine diphosphate ADP 3-methyl-1-hydroxybutyl-thiamin diphosphate CoA acetyl-CoA 1.3.99.10 | isovaleryl-CoA dehydrogenase 1.2.4.4 | 3-methyl-2-oxobutanoate dehydrogenase (E1) (leucine) 2.6.1.42 | branched-chain amino acid aminotransferase (leucine) 2.3.1.168 | 2-methylpropanoyl-CoA:dihydrolipamide-E S-(2-methylpropanoyl) transferase (E2) (leucine) 6.4.1.4 | 3-Methylcrotonyl-CoA-Carboxylase 4.1.3.4 | Hydroxymethylglutaryl-CoA-lyase 4.2.1.18 | methylglutaconyl-CoA hydratase 1.2.4.4 | 3-methyl-2-oxobutanoate dehydrogenase (E1) (leucine) 1.8.1.4 | dihydrolipoamide dehydrogenase (E3) (leucine)