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L-glutamate CO2 acetyl-CoA L-glutamate CO2 pyruvate 2-oxoglutarate (2S)-2-isopropyl-3-oxosuccinate NAD+ L-glutamate 2-acetolactate NADPH NADP+ 2-oxoisocaproate (R)-2,3-dihydroxy-isovalerate CoA NADH pyruvate L-alanine (2S)-2-isopropylmalate 2-oxoglutarate 2-oxoglutarate L-leucine (2R,3S)-3-isopropylmalate L-valine 2-oxoisovalerate 2.6.1.42 | branched-chain-amino-acid transaminase (leucine synthesis) 1.1.1.85 | 3-isopropylmalate dehydrogenase 2.2.1.6 | acetolactate synthase (valin synthesis) 4.2.1.9 | dihydroxy-acid dehydratase (valin synthesis) 2.6.1.42 | branched-chain-amino-acid transaminase (valine synthesis) 4.2.1.33 | 3-isopropylmalate dehydratase 2.6.1.2 | alanine transaminase 2.3.3.13 | 2-isopropylmalate synthase 1.1.1.86 | ketol-acid reductoisomerase (valin synthesis)
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